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Polysilanes are organosilicon compounds with the formula (R2Si)n. They are relatives of traditional organic polymers but their backbones are composed
Polysilane
Chemical compound
an industrial scale as the principal precursor to dimethylsilicone and polysilane compounds. The first organosilicon compounds were reported in 1863 by
Dimethyldichlorosilane
Anti-foaming agent used to reduce bloating, discomfort or pain caused by excessive gas
Kremil-S, Maalox Plus, Magasida, Mi-Acid, Mygel, Mylagen, Mylanta, Polysilane, Polysilane Delalande, Rumibex and Trial AG with alverine as Avarin, Meteospasmyl
Simeticone
Solid polymers of only silicon and hydrogen
replaced with organic substituents, particularly alkyl and aryl groups, polysilanes are obtained. Although organosilicon polymers can be considered structural
Polysilicon_hydride
Polymer whose backbone does not contain carbon
forms of the group IV elements are well known. The premier materials are polysilanes, which are analogous to polyethylene and related organic polymers. They
Inorganic_polymer
Indonesian actress
Syariah Lasegar Sunsilk Citra Citroën Ambeven Colidan Diapet Mylanta Polysilane Promag 2007: Commendable Actress (television) Festival Film Bandung 2007
Naysila_Mirdad
been demonstrated for the synthesis of certain disilanes as well as polysilanes. These reactions generally require catalysts. Titanocene and related
Dehydrogenative coupling of silanes
Dehydrogenative_coupling_of_silanes
Bonding of atoms of the same element into chains or rings
substituents in place of hydrogen on each silicon it is possible to prepare polysilanes (sometimes, erroneously called polysilenes) that are analogues of alkanes
Catenation
Reaction in organic chemistry
NaCl When applied to main group dihalides, rings and polymers result. Polysilanes and polystannanes are produced in this way n Me2SiCl2 + 2n Na → (Me2Si)n
Wurtz_reaction
Chemical compounds containing C–Li bonds
silyllithiums, extensively used in the synthesis of organometallic complexes and polysilane dendrimers. In the solid state, in contrast with alkyllithium reagents
Organolithium_reagent
Chemical compound
("Teflon"). Sodium–potassium alloy polymerizes dimethyldichlorosilane into polysilanes with a Si-Si backbone and methyl radicals, primarily dodecamethylcyclohexasilane:
Sodium–potassium_alloy
American chemist, engineer and materials scientist
Semiconductors and Semiconductor Superlattices, H Abstraction for Nanotechnology, Polysilane, and Growth of CVD Diamond (1994) Doctoral advisor William Andrew Goddard
Charles_Musgrave
Chemical compounds with at least one silicon atom
breaking of a C–H or C–C bond and the formation of radical intermediates, polysilanes decompose by eliminating silylenes :SiH 2 or :SiHR, as the activation
Silicon_compounds
Class of organosilicon compounds with the formula SiR4
triethylsilane (HSi(C 2H 5) 3) and triethoxysilane (HSi(OC 2H 5) 3). Polysilanes are organosilicon compounds with the formula (R 2Si) n. They feature
Silanes
Chemical compound
(1997-11-15). "Structure and optical properties of the planar silicon compounds polysilane and Wöhler siloxene". Physical Review B. 56 (20). American Physical Society
Siloxene
Family of inorganic polymers containing a tin-tin backbone
Structurally related but better characterized (and more useful) are the polysilanes (R2Si)n. Oligo- or polystannanes were first described by Löwig in 1852
Polystannane
Chemical compound
Si6(CH3)12. It is one of the more readily prepared and easily handled polysilanes. Dodecamethylcyclohexasilane is produced by reduction of dimethyldichlorosilane
Dodecamethylcyclohexasilane
polysilicon hydride is replaced with alkyl or aryl side-groups, the term polysilane is used. 3-Silylhexasilane, H3Si−SiH2−SiH(−SiH3)−SiH2−SiH2−SiH3, is the
Binary silicon-hydrogen compounds
Binary_silicon-hydrogen_compounds
Organic Chemistry involving Germanium
another route to organogermanium compounds. Akin to hydrocarbons and polysilanes, many organogermanium compounds are known with Ge-Ge bonds. An early
Organogermanium_chemistry
Chemical compound
also arise as the products of pyrolysis of preceramic polymers, namely polysilanes and polyethoxysilsesquiazane. SiON materials thus obtained are referred
Silicon_oxynitride
Dehydrogenative coupling of silanes, dihydro- and trihydrosilanes, to polysilanes has been investigated, although the technology has not been commercialized
Coordination_polymerization
American engineer & educator (1931–2011)
nuclear and electronic contributions to the optical nonlinearity in polysilanes," Appl. Phys. Lett. 54, 1713–1715 (1 May 1989). A. E. Siegman, P. L.
Anthony_E._Siegman
Chemical compound
analogs. Silylenes have been generated by thermolysis or photolysis of polysilanes, by silicon atom reactions (insertion, addition or abstraction), by pyrolysis
Silylene
Class of polymers with a silicon-nitrogen backbone
high performance materials. The most important pre-ceramic polymers are polysilanes [R2Si−SiR2]n, polycarbosilanes [R2Si−CH2]n, polysiloxanes [R2Si−O]n and
Polysilazane
American inorganic chemist
712–719. Tilley, T.D. "The Coordination Polymerization of Silanes to Polysilanes by a "σ-Bond Metathesis" Mechanism. Implications for Linear Chain Growth
Don_Tilley
Chemical compound
occur between two different silicon tetrahalides (as well as halogenated polysilanes) when heated to 100 ˚C, resulting in various mixed halosilanes. The melting
Silicon_tetrabromide
Chemical compound
trisilacyclopropanes. When the R group is not bulky, cyclic or polymeric, polysilanes are the products. In one study a disilene is prepared by an intramolecular
Disilene
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Boy/Male
Indian
Sublime, Lofty, High, Tall
Boy/Male
Tamil
Shwetanshu | à®·à¯à®µà¯‡à®¤à®¾à®¨à¯à®·à¯
The Moon
Boy/Male
Tamil
Mandhatri | மநà¯à®¤à®¾à®¤à¯à®°à¯€
Prince
Surname or Lastname
English (Kent)
English (Kent) : unexplained; perhaps a metathesized form of Twynam, a habitational name from Twinehame in Sussex or Twinham (now Christchurch) in Hampshire.
Boy/Male
Afghan, Arabic, German, Indian, Muslim, Pashtun, Sindhi
Lion; King of Jungle
Girl/Female
Hindu, Indian, Traditional
Goddess of Mind; Desire
Boy/Male
English American
Nickname for a red-haired person.
Boy/Male
Hindu, Indian, Marathi
Glorious; Shining; The Dawn
Surname or Lastname
English (now most common in northern Ireland)
English (now most common in northern Ireland) : probably a habitational name from a lost or unidentified place, most likely somewhere in Lancashire or Yorkshire.
Boy/Male
Gujarati, Hindu, Indian, Marathi
The First Ray of Light; Part of Parents; Gift of God
POLYSILANE
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POLYSILANE