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SILAZANE

Silazane

Class of chemical compounds

A silazane is a family of compounds with Si-N bonds. Usually the Si and N have organic substituents. They are analogous to siloxanes, with -NR- (R = alkyl

Silazane

Polysilazane

Class of polymers with a silicon-nitrogen backbone

reported in the 1940s, served as the cornerstone for the development of silazane chemistry. In the 1960s, the first attempts to transform organosilicon

Polysilazane

Organosilicon chemistry

Organometallic compound containing carbon–silicon bonds

unstable. Analogous compounds with nitrogen instead of oxygen are the silazanes. Silyl ethers have the connectivity Si–O–C. They are typically prepared

Organosilicon chemistry

Organosilicon_chemistry

Open-chain compound

Type of organic molecule with a linear structure

PMID 5645558. IUPAC, Compendium of Chemical Terminology, 5th ed. (the "Gold Book") (2025). Online version: (2006–) "silazanes". doi:10.1351/goldbook.S05669

Open-chain compound

Open-chain_compound

Thiol-ene reaction

Formation of a thioether (–S–) compound from a thiol (–SH) and an alkene ( >C=C< )

rate-limiting step, while in the case of less reactive alkenes, such as vinyl silazanes, propagation is the rate-limiting step. The thiol's hydrogen affinity

Thiol-ene reaction

Thiol-ene_reaction

Transition metal silyl complexes

Bis(silyl)mercury reagents behave similarly. Acidic metal hydrides can condense with silazanes, but the reverse-polarity reaction between a silane and an amino complex

Transition metal silyl complexes

Transition_metal_silyl_complexes