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Organosulfur compound of the form >C(S–)O– or >C(S–)2
In organosulfur chemistry, a thioketal is the sulfur analogue of a ketal (R2C(OR)2), with one of the oxygen replaced by sulfur (as implied by the thio-
Thioketal
Chemical reaction
The Mozingo reduction, also known as Mozingo reaction or thioketal reduction, is a chemical reaction capable of fully reducing a ketone or aldehyde to
Mozingo_reduction
Organosulfur compounds of the form –CH(O–)S– or –CH(S–)2
halides rearranges dithioacetals to dithioacyloins. Mozingo reduction Thioketal IUPAC, Compendium of Chemical Terminology, 5th ed. (the "Gold Book") (2025)
Thioacetal
Any organic compound having a sulfanyl group (–SH)
15227/orgsyn.021.0036. S. R. Wilson, G. M. Georgiadis (1990). "Mecaptans from Thioketals: Cyclododecyl Mercaptan". Organic Syntheses; Collected Volumes, vol. 7
Thiol
Removal of sulfur from a substance
environment. A laboratory scale hydrogenolysis is the desulfurization of thioketals by Raney nickel. In such cases, the hydrogen is contained within the reagent
Desulfurization
Organic compound with the structure >C(O–)2
compounds of type R1R2C(SR)(SR') (R,R' ≠ H), also known as thioacetal and thioketals. Hemiaminal Orthoformate IUPAC, Compendium of Chemical Terminology, 5th
Acetal
Class of enzymes
involves a 1,2 nucleophilic addition. This reaction, the formation of a thioketal, transforms the enzyme from its inactive to active state. Inhibition of
Pyruvate_decarboxylase
Medication
Organometallic addition of the acetylene was the next step (10). Cleavage of the thioketal in the presence of sodium metal in liquid ammonia completed the synthesis
Desogestrel
Organic compounds that contain sulfur
by action of elemental sulfur and aluminium chloride. Thioacetals and thioketals feature C−S−C−S−C bond sequence. They represent a subclass of sulfides
Organosulfur_chemistry
Reduction method involving hydrazine
reduction can be employed when formation of the hydrazone fail, including thioketal reduction with Raney nickel or reaction with sodium triethylborohydride
Wolff–Kishner_reduction
Chemical compound
15227/orgsyn.070.0240. Wilson, S. R.; Georgiadis, G. M. (1983). "Mercaptans from Thioketals: Cyclododecyl Mercaptan". Organic Syntheses. 61: 74. doi:10.15227/orgsyn
1,3-Dithiolane
German chemist (1846–1896)
influenced the organosulfur chemistry by the synthesis of thioacetals and thioketals. These substances were subsequently used by other scientists, for example
Eugen_Baumann
Chemical reaction in which a C–C or C–R bond is cleaved by hydrogen
involves the cleavage of benzyl ethers: R−OCH2C6H5 + H2 → R−OH + CH3C6H5 Thioketals undergo hydrogenolysis using Raney nickel in the Mozingo reduction. Laboratory
Hydrogenolysis
Method of controlled drug release
species (ROS). Bonds that are able to be cleaved by ROS are generally thioketals, ketals, and diselenides. Enzyme responsive gated materials are another
Gated_drug_delivery_systems
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