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Search references for ALLYL GROUP. Phrases containing ALLYL GROUP
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Chemical group (–CH2–CH=CH2)
chemistry, an allyl group is a substituent with the structural formula −CH2−HC=CH2. It consists of a methylene bridge (−CH2−) attached to a vinyl group (−CH=CH2)
Allyl_group
Transition-metal allyl complexes are coordination complexes with allyl and its derivatives as ligands. The allyl group, the connectivity CH2=CHCH2−, binds
Transition metal allyl complex
Transition_metal_allyl_complex
Organic substituent with one or more free valences at a carbon atom
Acetonyl group Acyl group (e.g. acetyl group, benzoyl group) Alkyl group (e.g. methyl group, ethyl group) Alkenyl group (e.g. vinyl group, allyl group) Alkynyl
Organyl_group
Organic compound (CH2=CHCH2OH)
Allyl alcohol (IUPAC name: prop-2-en-1-ol) is an organic compound with the structural formula CH2=CHCH2OH. Like many alcohols, it is a water-soluble,
Allyl_alcohol
Chemical compound
Allyl bromide (3-bromopropene) is an organic halide. It is an alkylating agent used in synthesis of polymers, pharmaceuticals, perfumes and other organic
Allyl_bromide
Chemical compound
routes are the oxidation of the allyl side chain and the oxidation of the methylenedioxy group. The oxidation of the allyl side chain is mediated by a cytochrome
Safrole
Topics referred to by the same term
Committee in South Korea Awl (disambiguation) Alle (disambiguation) Allyl group "For all", a universal quantification in predicate logic, represented
All
Palladium-catalysed substitution reaction
substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative
Tsuji–Trost_reaction
Chemical compound
structure consists of a benzene ring substituted with a methoxy group and an allyl group. It is an isomer of anethole, differing with respect to the location
Estragole
Chemical compound
Allyl chloride is the organic compound with the formula CH2=CHCH2Cl. This colorless liquid is insoluble in water but soluble in common organic solvents
Allyl_chloride
Group of atoms giving a molecule characteristic properties
etc. There are several functional groups that contain an alkene such as vinyl group, allyl group, or acrylic group. Hydrocarbons may form charged structures:
Functional_group
Seventh letter in the Greek alphabet
coordination compound. For example, an allyl group can coordinate to palladium in the η¹ mode (only one atom of an allyl group attached to palladium) or the η³
Eta
Chemical compound
introducing the allyl group. It is commonly available as a solution in diethyl ether. It may be synthesized by treatment of magnesium with allyl bromide while
Allylmagnesium_bromide
Chemical compound
It is a colorless liquid. The compound consists of a phenyl group attached to an allyl group. Allylbenzene isomerizes to trans-propenylbenzene. In plant
Allylbenzene
Chemical reaction
chemical reaction discovered by Rainer Ludwig Claisen. The heating of an allyl vinyl ether will initiate a [3,3]-sigmatropic rearrangement to give a γ
Claisen_rearrangement
Index of chemical compounds with the same name
containing a phenyl ring bonded to propene, more specifically those with an allyl group bonded to a benzene ring, having the parent structure of allylbenzene
Phenylpropene
Chemical compound
condensation product of allyl alcohol and glycidol via an ether linkage. Because it contains both an alkene and an epoxide group, either group can be reacted selectively
Allyl_glycidyl_ether
Chemical group (–CH=CH2)
functional groups. On a carbon skeleton, sp2-hybridized carbons or positions are often called vinylic. Allyls, acrylates and styrenics contain vinyl groups. (A
Vinyl_group
Hydrocarbon compound containing one or more C=C bonds
recognizes two names for hydrocarbon groups containing carbon–carbon double bonds, the vinyl group and the allyl group. Many of the physical properties of
Alkene
Reaction in organic chemistry
relatively electron-rich allyl group (the ene) and an electron-poor π bond (the enophile). The reaction is a pericyclic group transfer; the enophile attacks
Ene_reaction
Chemical compound
reaction of allyl magnesium bromide with anhydrous nickel chloride. It was first prepared similarly by Gunther Wilke et al. The same group reported that
Bis(allyl)nickel
allylation involves the enantioselective iridium-catalyzed addition of an allyl group to an aldehyde or an alcohol, resulting in the formation of a secondary
Krische_allylation
Plastic
Poly(allyl diglycol carbonate) (PADC) is a thermosetting plastic commonly used in the manufacture of eyeglass lenses alongside the material PMMA (polymethyl
CR-39
Opioid analgesic
The decreased potency of this analogue caused by the addition of the allyl group makes it somewhat less dangerous than fentanyl itself (ED50(rat) of 80μg/kg
3-Allylfentanyl
Organosilicon compound
(CH3)3SiCH2CH=CH2. The molecule consists of the trimethylsilyl group attached to allyl group. This colorless liquid is used in organic synthesis. "Allyltrimethylsilane"
Allyltrimethylsilane
Index of chemical compounds with the same name
namely allyl fluoride (Allyl fluoride [Wikidata]), allyl chloride, allyl bromide, and allyl iodide. Selective bromination of alkenes in the allyl position
Allyl_halide
Chemical compound
This is due to syringol's allyl aromatic ether being blocked by ethers in both ortho-positions. When blocked the allyl group migrates to the para-position
Elemicin
Organosulfur compound
Allyl methyl sulfide is an organosulfur compound with the chemical formula CH2=CHCH2SCH3. The molecule features two functional groups, an allyl (CH2=CHCH2)
Allyl_methyl_sulfide
Type of organic chemical reaction
trans to the adjacent methyl group. Allyl shifts can also take place with electrophiles. In the example below the carbonyl group in benzaldehyde is activated
Allylic_rearrangement
Chemical compound
Allyl acetate is an organic compound with formula C3H5OC(O)CH3. This colourless liquid is a precursor to especially allyl alcohol, which is a useful industrial
Allyl_acetate
Index of chemical compounds with the same molecular formula
(molar mass: 41.07 g/mol, exact mass: 41.0391 u) may refer to: Allyl group Cyclopropyl group This set index page lists chemical structure articles associated
C3H5
Preferential formation of one chiral isomer over another in a chemical reaction
the carbonyl group placed trans to the ethyl group (the large group) and the allyl boron approaching past the hydrogen (the small group). The structure
Asymmetric_induction
"Palladium-mediated decarboxylative aldol reaction with allyl β-keto carboxylates"). The allyl group can be removed by palladium, following decarboxylation
Modified aldol tandem reaction
Modified_aldol_tandem_reaction
Opioid analgesic drug
and test) of 101–310×. It may be of interest to researchers that the allyl group in this compound and in allylprodine overlay very closely. 14-Phenylpropoxymetopon
14-Cinnamoyloxycodeinone
Chemical compound
oxygen atoms, a 2,4,8,10-tetraoxaspiro[5.5]undecane which carries one allyl group in each of the 3 and 9 positions. Condensation products from propenal
3,9-Divinyl-2,4,8,10-tetraoxaspiro(5.5)undecane
3,9-Divinyl-2,4,8,10-tetraoxaspiro(5.5)undecane
Acrylating agent
odor. Its structure contains allyl groups and a functional carbonate group. The presence of double bonds in the allyl groups makes it reactive in various
Diallyl_carbonate
American organic chemist (1909–1966)
also developed a reaction involving the thermal rearrangement of an allyl group which eventually became known as the Cope rearrangement. In 1941, Cope
Arthur_C._Cope
Chemical synthesis of nucleic acids
the 3′-O-allyl group prevents further extension, thereby enabling single-nucleotide addition per cycle. Chemical removal of the blocking group then permits
Oligonucleotide_synthesis
Representation method in chemistry
isopropyl group All for the allyl group (uncommon) Bu, n-Bu or nBu for the (normal) butyl group i-Bu or iBu (i often italicized) for the isobutyl group s-Bu
Skeletal_formula
crotylate group. Crotyl halides, crotyl alcohols, crotyl silanes, crotonaldehyde and crotyl boronates are useful reagents for synthesizing crotyl and allyl compounds
Crotyl_group
is a chemical reaction that involves the nucleophilic addition of an allyl group to an aldehyde. The catalyst is a chiral complex that contains titanium
Keck_asymmetric_allylation
Chemical reaction in organic chemistry
more appropriate. If the ylide carbon is substituted with an aryl or allyl group, the reagent is referred to as a semi-stabilized ylide. These have been
Johnson–Corey–Chaykovsky reaction
Johnson–Corey–Chaykovsky_reaction
Chemical group (–CH2C≡CH)
propargylic group and thus two bonds from an alkyne moiety. a 3-butynyl fragment, HC≡C−CH2CH2−, or substituted homologue. Alkenyl groups Allyl Vinyl group Ethynyl
Propargyl_group
Non-depolarizing neuromuscular blocker
pancuronium; hence its monoquaternary structure and its having an allyl group and a pyrrolidine group attached to the D ring quaternary nitrogen atom. Rocuronium
Rocuronium_bromide
Chemical reaction
allyl shift via a beta-silyl carbocationic intermediate, the beta-silicon effect. Allylation of a carbonyl ketone (compound containing a ketone group
Sakurai_reaction
Free radical
has the formula CH2=(C·)–CH3. These groups are found in many compounds. Propenyl compounds are isomeric with allyl compounds, which have the formula ·CH2–CH=CH2
Propenyl_group
Chemical compound
reaction of allyl chloride with copper-silicon alloy. The compound is bifunctional, containing reactive trichlorsilyl and allyl groups. The SiCl3 group undergoes
Allyltrichlorosilane
"The Introduction of Substituted Vinyl Groups. V. A Rearrangement Involving the Migration of an Allyl Group in a Three-Carbon System". Journal of the
List_of_organic_reactions
Chemical synthesis
compound was reduced to the allyl alcohol 25 using Lindlar catalyst, and lithium aluminium hydride removed the remaining amide group to furnish 26. An allylic
Strychnine_total_synthesis
Opioid analgesic drug
and the 3R,4S-isomer is 23 times more potent than morphine, due to the allyl group binding to an additional amino acid target in the binding site on the
Allylprodine
Chemical compound
no other important hormonal activity. The medication is a prodrug of 17α-allyl-19-nortestosterone (3-ketoallylestrenol) in the body. Allylestrenol was
Allylestrenol
Chemical compound
material before breaking), and also acts as a chain extender due to the allyl groups that can form cross-links between PVC chains. DAP is a plasticizer used
Diallyl_phthalate
Organometallic compound (Pb(C2H3O2)4)
mechanism the allyl group is first converted to a trioxalane according to conventional ozonolysis which then interacts with the alkoxy lead group. Myrboh,
Lead(IV)_acetate
Process to transform the material properties of natural rubber
that the reactive sites, often referred to as 'cure sites', are the allyl groups (-CH=CH-CH2-). Sulfur forms bridge between these sites, crosslinking
Sulfur_vulcanization
norethisterone), allyl group (e.g., allylestrenol), or vinyl group (e.g., norvinisterone) all dramatically reduce AR agonist activity. A propyl group (e.g., topterone
Structure–activity relationships of anabolic steroids
Structure–activity_relationships_of_anabolic_steroids
Drug class
substituents, such as allyl- or cyclopropyl methyl at the morphinan nitrogen, while agonists generally contain a methyl group. On the other hand, agonist
Peripherally acting μ-opioid receptor antagonist
Peripherally_acting_μ-opioid_receptor_antagonist
Organic compound of the form R–B(OH)2
insertion of an RCH2 group into the C-B bond. Another reaction featuring a boronate alkyl migration is the Petasis reaction. Allyl boronic esters engage
Boronic_acid
copolymers Actinomycin D Agaritine Aldicarb Aldrin Allyl chloride Allyl isothiocyanate Allyl isovalerate Amaranth (dye) 5-Aminoacenaphthene 2-Aminoanthraquinone
IARC_group_3
Organometallic chemical reaction
can be, but are not limited to, an alkyl, aryl, alkynyl, allyl, halogen, or pseudohalogen group. The reaction is usually an irreversible process due to
Transmetalation
Canadian-American chemist (1915–2008)
scientists. The Introduction of Substituted Vinyl Groups. V. A Rearrangement Involving the Migration of an Allyl Group in a Three-Carbon System. Arthur C. Cope
Elizabeth_Hardy_(chemist)
Chemical compound
monocarboxylic acid, an aromatic ether in which the ether oxygen links an allyl group to the 4-position of the aromatic ring of (3-chlorophenyl)acetic acid
Alclofenac
Chemical structure derived from cyclopropane
methyl cation's HOMO isolobal to the allyl anion's HOMO. Zvi Rappoport (Ed.), The Chemistry of the Cyclopropyl Group, Band 1, Wiley, Chichester u. a. O
Cyclopropyl_group
Chemical reaction
"The Introduction of Substituted Vinyl Groups. V. A Rearrangement Involving the Migration of an Allyl Group in a Three-Carbon System". J. Am. Chem. Soc
Oxy-Cope_rearrangement
Chemical compound
widely used transition metal allyl complexes. The compound has a dimeric structure that is centrosymmetric. Each allyl group lies in a plane at an angle
Allylpalladium_chloride_dimer
Chemical compound
Allyl cyanide is an organic compound with the formula CH2CHCH2CN. Like other small alkyl nitriles, allyl cyanide is colorless and soluble in organic solvents
Allyl_cyanide
Chemistry of compounds with a carbon-indium bond
two steps: first, indium reacts with the allyl halide, give an allyl-In(III) intermediate, second, this allyl indide reacts with an electrophile: The reaction
Organoindium_chemistry
Pharmaceutical compound
(April 2025). "Synthesis and analytical characterization of 1-(2-thienoyl)-6-allyl-nor-d-lysergic acid diethylamide (1T-AL-LAD)". Drug Testing and Analysis
1D-AL-LAD
Chemical reaction
organic chemistry and involves the transformation of a β-keto allyl ester into a α-allyl-β-ketocarboxylic acid. This organic reaction is accompanied by
Carroll_rearrangement
Chemical reaction used in organic synthesis
further work on the coupling of allyl-tin reagents with both aryl (C) and acyl (D) halides. The greater ability of allyl groups to migrate to the palladium
Stille_reaction
electrophile on an allyl- or vinylsilane. An allyl or vinyl group is incorporated at the electrophilic center after loss of the silyl group. In 1948, it was
Electrophilic substitution of unsaturated silanes
Electrophilic_substitution_of_unsaturated_silanes
allyl is favored, the regioselectivity of nucleophilic attack can heavily depend on the exact nature of ligands positioned trans to the allyl group.
Telomerization_(dimerization)
Oxygen with all of its electrons spin paired
reactions with alkenic allyl groups, e.g., citronella, shown, by abstraction of the allylic proton, in an ene-like reaction, yielding the allyl hydroperoxide,
Singlet_oxygen
usually more facile than C-H oxidation, although sterically hindered allyl groups may undergo selective C-H oxidation instead of epoxidation of the allylic
Oxidation_with_dioxiranes
Chemical compound
Sinigrin or allyl glucosinolate is a glucosinolate that belongs to the family of glucosides found in some plants of the family Brassicaceae such as Brussels
Sinigrin
Pharmaceutical compound
4-Allyl-6-oxa-noribogainalog is a κ-opioid receptor (KOR) agonist of the oxa-ibogalog family related to oxa-noribogaine. It is a highly potent full agonist
4-Allyl-6-oxa-noribogainalog
Chemical group derived from alkanes (one hydrogen removed)
In organic chemistry, an alkyl group is an alkane missing one hydrogen atom. The term alkyl is intentionally unspecific to include many possible substitutions
Alkyl_group
Chemical reaction used to create phenols
presence of exactly one equivalent of palladium catalyst (from which the allyl group adds into the final aromatic structure) is crucial for the catalyzed
Danheiser_benzannulation
the nucleophile on a η3 isomer. The nature of the substituents of the allyl group can strongly affect the kinetics and regiochemistry of the nucleophilic
Transition metal indenyl complex
Transition_metal_indenyl_complex
Chemical compound
sesamol with potassium carbonate and allyl bromide, followed by a thermal Claisen rearrangement to move the O-allyl group onto the adjacent site on the aromatic
Carpanone
Class of enzymes
In enzymology, an allyl-alcohol dehydrogenase (EC 1.1.1.54) is an enzyme that catalyzes the chemical reaction Allyl alcohol + NADP+ H+ H+ Acrolein
Allyl-alcohol_dehydrogenase
Austrian chemist (1820–1864)
garlic oil, piperine, quinine and coniine in Liebig's Annalen der Chemie. Allyl group Diallyl disulfide Carl Oppenheimer (1897). "Theodor Wertheim". Allgemeine
Theodor_Wertheim
Photochemical reaction
Formally, it amounts to a 1,2 shift of one ene group (in the diene) or the aryl group (in the allyl-aromatic analog), followed by bond formation between
Di-π-methane_rearrangement
Categorization of chemical reactions
retention of configuration. With certain allyl aryl ethers a competing reaction takes place. The reaction of allyl phenyl ether 1 with sec-butyllithium at
1,2-Wittig_rearrangement
Reaction in organic chemistry
carbene reacts with an allyl compound with transposition of the alkene and transfer of the electronegative group from the allyl onto the carbene carbon
Doyle–Kirmse_reaction
Branch of chemistry
type (allyl)BaCl can be prepared by reaction of activated barium (Rieke method reduction of barium iodide with lithium biphenylide) with allyl halides
Group 2 organometallic chemistry
Group_2_organometallic_chemistry
reagent of allyl bromide in a nucleophilic addition aided by zinc(II) chloride, which blocked the Grignard from attack on carbonate group, to alcohol
Wender_Taxol_total_synthesis
Chemical compound
17α-allyltestosterone, or of 17α-allyl-19-nortestosterone. It is one of only two marketed progestins that possesses a 17α-allyl group, the other being allylestrenol
Altrenogest
Chemical compound
diluents and elastomers. Epichlorohydrin is traditionally manufactured from allyl chloride in two steps, beginning with the addition of hypochlorous acid
Epichlorohydrin
ketone groups for a pinacol coupling which were realized by oxidation of the C11 alcohol (TPAP, NMO) to ketone 36 and Wacker oxidation of the allyl group to
Mukaiyama Taxol total synthesis
Mukaiyama_Taxol_total_synthesis
Chemical group (–CH2–C6H5)
R−CH2−C6H5. Benzyl features a benzene ring (C6H6) attached to a methylene group (−CH2−). In IUPAC nomenclature, the prefix benzyl refers to a C6H5CH2 substituent
Benzyl_group
allyls. After complete polymerization, typically by UV micromolding, the polymer articles contain a well-defined number of unreacted thiol or allyl groups
Off-stoichiometry thiol-ene polymer
Off-stoichiometry_thiol-ene_polymer
thiocyanate group as a whole with hydride. Some thiocyanates isomerize to the isothiocyanates. This reaction is especially rapid for the allyl isothiocyanate:
Organic_thiocyanates
Coupling reaction used in organic synthesis
coupling reaction forming an alcohol from the reaction of an aldehyde with an allyl or vinyl halide. In their original 1977 publication, Tamejiro Hiyama and
Nozaki–Hiyama–Kishi_reaction
Chemical compound
properties are similar to those of allyl chloride. It is a strong alkylating agent used to install isobutenyl groups. It is also a precursor to methallyl
Methallyl_chloride
Chemical group (–CH2–CH3)
In organic chemistry, an ethyl group (abbreviated as ET, Et or et) is an alkyl substituent with the formula −CH2CH3, derived from ethane (C2H6). Ethyl
Ethyl_group
Chemical group (–C3H7) derived from propane
In organic chemistry, a propyl group is a three-carbon alkyl substituent with chemical formula −CH2CH2CH3 for the linear form. This substituent form is
Propyl_group
Organometallic coupling reaction
classical definition, carbon alkyl, allyl, vinyl, or aryl magnesium halides (Grignard reagent) are added to the carbonyl groups of either an aldehyde or ketone
Grignard_reaction
Chemical compound
distinctive odor. It is a thioester of a sulfinic acid. It is also known as allyl thiosulfinate. Its biological activity can be attributed to both its antioxidant
Allicin
Functional group (C=O)
In organic chemistry, a carbonyl group is a functional group with the formula C=O, composed of a carbon atom double-bonded to an oxygen atom, and it is
Carbonyl_group
Chemical group (R–O)
alkoxy group is an alkyl group which is singularly bonded to oxygen; thus R−O. Denoted usually with apostrophe ('). The range of alkoxy groups is vast
Alkoxy_group
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ALLYL GROUP
ALLYL GROUP
Girl/Female
German, Teutonic
Noble; Kind; Noble Humor
Boy/Male
Australian, Celtic
Harmony; Stone; Noble; Fair; Handsome; Originally a Saint's Name; Diminutive of Alan
Boy/Male
Muslim
Ally, Confederate
Surname or Lastname
Muslim
Muslim : variant spelling of Ali.English and French : variant spelling of Alley.
Boy/Male
Muslim
Ally, Confederate
Girl/Female
French American English
A 13th centurymeaning nobility. Now particularly popular in Scotland.
Girl/Female
Native American American
Friend; ally.
Boy/Male
Indian
Ally, Confederate
Girl/Female
Irish Gaelic
Beautiful.
Boy/Male
Muslim
Kind. Ally.
Girl/Female
Teutonic
Noble humor.
Boy/Male
Celtic American English
Handsome.
Boy/Male
Arabic, Muslim
Comforter
Male
English
English variant spelling of Celtic Alan, possibly ALLYN means "little rock."Â
Female
English
Scottish pet form of Norman French Alison, ALLY means "noble sort."
Girl/Female
American, British, Christian, Danish, English, German, Greek, Swedish
Noble and Shining; Noble; Nobility; Feminine of Alexander; High; Defender of Man
Boy/Male
American, Australian, Christian, Gaelic, Irish
Handsome; Comely; Little Rock
Boy/Male
Muslim
Kind. Ally.
Surname or Lastname
English
English : variant of Allen, established in New England in the 17th century.Matthew Allyn was one of the founders of Hartford, CT, (coming from Cambridge, MA, with Thomas Hooker) in 1635.
Boy/Male
Celtic Gaelic
Harmony, stone, or noble. Also fair, handsome. Originally a saint's name, it was reintroduced to...
ALLYL GROUP
ALLYL GROUP
ALLYL GROUP
ALLYL GROUP
ALLYL GROUP
ALLYL GROUP
ALLYL GROUP
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