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Chemical compound
Dimethoxytrityl, often abbreviated DMT, is a protecting group widely used for protection of the 5'-hydroxy group in nucleosides, particularly in oligonucleotide
Dimethoxytrityl
Chemical compound
oligonucleotide synthesis during the "deblocking" step to remove the dimethoxytrityl protecting group from the growing DNA/RNA strand for the next nucleotide
Trichloroacetic_acid
Geometric aspects of ions and molecules affecting their shape and reactivity
the presence of a free secondary 3'-hydroxy group as a result of steric hindrance due to the dimethoxytrityl group and the ribose ring (Py = pyridine).
Steric_effects
Topics referred to by the same term
5-triazin-2-yl)-4-methyl-morpholinium chloride) an amide-coupling reagent Dimethoxytrityl, a protecting group used in oligonucleotide synthesis Deadman timer
DMT_(disambiguation)
Derivatives of nucleosides
neutral conditions. For instance, half-life of 2-cyanoethyl 5'-O-(4,4'-dimethoxytrityl)thymidine-3'-O-(N,N-diisopropylamino)phosphite in 95% aqueous acetonitrile
Nucleoside_phosphoramidite
Group of atoms introduced into a compound to prevent subsequent reactions
Removed via oxidation with DDQ or ceric ammonium chloride Acetals: Dimethoxytrityl, [bis-(4-methoxyphenyl)phenylmethyl] (DMT) — Removed by weak acid.
Protecting_group
Chemical synthesis of nucleic acids
reviewed: The 5'-hydroxyl group is protected by an acid-labile DMT (4,4'-dimethoxytrityl) group. Thymine and uracil, nucleic bases of thymidine and uridine
Oligonucleotide_synthesis
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