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HALONIUM ION

  • Halonium ion
  • Any onium ion containing a halogen atom carrying a positive charge

    A halonium ion is any onium ion containing a halogen atom carrying a positive charge. This cation has the general structure R−+X−R′ where X is any halogen

    Halonium ion

    Halonium ion

    Halonium_ion

  • Halogen addition reaction
  • Reaction which adds a halogen molecule

    "Stable carbonium ions. XLVIII. Halonium ion formation via neighboring halogen participation. Tetramethylethylene halonium ions". Journal of the American

    Halogen addition reaction

    Halogen_addition_reaction

  • Onium ion
  • Class of positively-charged molecules

    ions such as iminium and nitrilium. A simple onium ion has a charge of +1. A larger ion that has two onium ion subgroups is called a double onium ion

    Onium ion

    Onium_ion

  • Fluoronium
  • Ion

    open-chain halonium ions (such as [Me2Cl]+[Al(OTeF5)4]–) as well as cyclic haliranium ions, fluorine was not believed to form fluoronium ions of type R–+F–R

    Fluoronium

    Fluoronium

    Fluoronium

  • Fürst–Plattner rule
  • Rule in organic chemistry

    derivatives. Cyclohexene derivatives, such as imines, epoxides, and halonium ions, react with nucleophiles in a stereoselective fashion, affording trans-diaxial

    Fürst–Plattner rule

    Fürst–Plattner_rule

  • Semipinacol rearrangement
  • Rearrangement reaction in organic chemistry

    electrophilic addition to the alkene group with electrophiles such as halonium ions, Brønsted acids and Lewis acids. In type 3 the substrates are epoxides

    Semipinacol rearrangement

    Semipinacol_rearrangement

  • Lactam
  • Cyclic amide

    derivatives from the nucleophilic abstraction reaction. An iminium ion reacts with a halonium ion formed in situ by reaction of an alkene with iodine. Lactams

    Lactam

    Lactam

  • Fluoroantimonate
  • Chemical compound

    Olah's work with this reaction established experimental evidence for halonium ions, which had been theoretically predicted to explain the regioselectivity

    Fluoroantimonate

    Fluoroantimonate

  • Alkene
  • Hydrocarbon compound containing one or more C=C bonds

    reactions do not require catalysts. The reaction occurs in two steps, with a halonium ion as an intermediate. Bromine test is used to test the saturation of hydrocarbons

    Alkene

    Alkene

    Alkene

  • Electrophilic halogenation
  • Chemical reaction in which halogen substituents are added to aromatic molecules

    formation of the arenium ion results in the temporary loss of aromaticity, which has a higher activation energy compared to halonium ion formation in alkenes

    Electrophilic halogenation

    Electrophilic_halogenation

  • Iodolactonization
  • Chemical reaction

    The reaction mechanism involves the formation of a positively charged halonium ion in a molecule that also contains a carboxylic acid (or other functional

    Iodolactonization

    Iodolactonization

  • Halogenation
  • Chemical reaction which adds one or more halogen elements to a compound

    2 H2O The addition of halogens to alkenes proceeds via intermediate halonium ions. In special cases, such intermediates have been isolated. Bromination

    Halogenation

    Halogenation

  • Leaving group
  • Atom(s) that detach from the substrate during a chemical reaction

    reductive elimination. Prominent hyper leaving groups include various halonium ions, such as diaryl iodonium salts; and other λ3-iodanes. Hyper leaving

    Leaving group

    Leaving group

    Leaving_group

  • Aurora Australis (icebreaker)
  • Australian icebreaker and research ship

    zero visibility in the engine room and was suppressed by the release of halonium ion fire suppression system. Re-entry to the compartment resulted in successful

    Aurora Australis (icebreaker)

    Aurora Australis (icebreaker)

    Aurora_Australis_(icebreaker)

  • Ylide
  • Organic compound

    dinitrogen. Stable carbenes also have a ylidic resonance contributor, e.g.: Halonium ylides can be prepared from allyl halides and metal carbenoids. After a

    Ylide

    Ylide

  • Hypervalent organoiodine compounds
  • Organic derivative of iodine

    (2017-07-01). "Halogen bonding in hypervalent iodine and bromine derivatives: halonium salts". IUCrJ. 4 (4): 411–419. doi:10.1107/S2052252517004262. ISSN 2052-2525

    Hypervalent organoiodine compounds

    Hypervalent_organoiodine_compounds

  • Trifluoromethylation
  • Chemical compound

    Leblanc, Danielle; Morton, Thomas Hellman (1 November 2002). "Gas-Phase Halonium Metathesis and Its Competitors. Skeletal Rearrangements of Cationic Adducts

    Trifluoromethylation

    Trifluoromethylation

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  • Ionnes
  • Boy/Male

    Hebrew

    Ionnes

    Gift from God.

    Ionnes

  • Ionna
  • Girl/Female

    Ukrainian

    Ionna

    God's gift.

    Ionna

  • Ion
  • Boy/Male

    Greek

    Ion

    Son of Apollo.

    Ion

  • Yavan | யாவாந
  • Boy/Male

    Tamil

    Yavan | யாவாந

    The ionians, Greeks

    Yavan | யாவாந

  • IONAS
  • Male

    Greek

    IONAS

    (Ἰωνᾶς) Greek form of Hebrew Yonah, IONAS means "dove." In the bible, this is the name of the father of Peter.

    IONAS

  • Musson
  • Surname or Lastname

    English (East Midlands)

    Musson

    English (East Midlands) : of uncertain origin, ostensibly a patronymic, though Reaney believes it to be a nickname from Anglo-Norman French muisson ‘sparrow’.French : variant of Musset (see Mussett 1).French : nickname from Old French moisson, mousson, ‘sparrow’.French : habitational name from Mousson in Meuse-et-Moselle, named with the Latin personal name Montius + the suffix -onem, or alternatively, with Latin mons ‘mountain’ + the suffix -ionem.

    Musson

  • IONATAN
  • Male

    Romanian

    IONATAN

    Romanian form of Hebrew Yownathan, IONATAN means "God has given." 

    IONATAN

  • ION
  • Male

    Romanian

    ION

    Basque and Romanian form of Greek Ioannes, ION means "God is gracious." In use by the Romani.

    ION

  • Ion
  • Surname or Lastname

    Romanian

    Ion

    Romanian : from the personal name Ion (see John).English : probably a variant of John.

    Ion

  • Ionia
  • Girl/Female

    Greek

    Ionia

    Amethyst.

    Ionia

  • IONEL
  • Male

    Romanian

    IONEL

    Pet form of Romanian Ioan, IONEL means "God is gracious."

    IONEL

  • IONATÁN
  • Male

    Irish

    IONATÁN

    Irish form of Hebrew Yownathan, IONATÁN means "God has given." 

    IONATÁN

  • Jonas
  • Surname or Lastname

    English, German, French, Jewish (Ashkenazic), Lithuanian, Czech and Slovak (Jonáš), and Hungarian (Jónás)

    Jonas

    English, German, French, Jewish (Ashkenazic), Lithuanian, Czech and Slovak (Jonáš), and Hungarian (Jónás) : from a medieval personal name, which comes from the Hebrew male personal name Yona, meaning ‘dove’. In the book of the Bible which bears his name, Jonah was appointed by God to preach repentance to the city of Nineveh, but tried to flee instead to Tarshish. On the voyage to Tarshish, a great storm blew up, and Jonah was thrown overboard by his shipmates to appease God’s wrath, swallowed by a great fish, and delivered by it on the shores of Nineveh. This story exercised a powerful hold on the popular imagination in medieval Europe, and the personal name was a relatively common choice. The Hebrew name and its reflexes in other languages (for example Yiddish Yoyne) have been popular Jewish personal names for generations. There are also saints, martyrs, and bishops called Jonas venerated in the Orthodox Church. Ionas is found as a Greek family name.Jewish (Ashkenazic) : respelling of Yonis, with Yiddish possessive -s.

    Jonas

  • IONUT
  • Male

    Romanian

    IONUT

    Pet form of Romanian Ioan, IONUT means "God is gracious."

    IONUT

  • IONELA
  • Female

    Romanian

    IONELA

    Variant spelling of Romanian Ioanela, IONELA means "God is gracious."

    IONELA

  • Iona
  • Boy/Male

    Welsh

    Iona

    Legendary king of France.

    Iona

  • IONA
  • Female

    Scottish

    IONA

     Scottish name derived from the name of an island in the Hebrides, ultimately from Old Norse ey, IONA means "island." Compare with another form of Iona.

    IONA

  • Iona
  • Girl/Female

    Irish

    Iona

    St. Colmcille founded his monastery on Iona, the island between Ireland and Scotland in 563 AD and thus the name is associated with “blessed.”

    Iona

  • Harrington
  • Surname or Lastname

    English

    Harrington

    English : habitational name from places in Cumbria, Lincolnshire, and Northamptonshire. The first gets its name from Old English Haferingtūn ‘settlement (Old English tūn) associated with someone called Hæfer’, a byname meaning ‘he-goat’. The second probably meant ‘settlement (Old English tūn) of someone called Hæring’. Alternatively, the first element may have been Old English hæring ‘stony place’ or hāring ‘gray wood’. The last, recorded in Domesday Book as Arintone and in 1184 as Hederingeton, is most probably named with an unattested Old English personal name, Heathuhere.Irish (County Kerry and the West) : adopted as an Anglicized form of Gaelic Ó hArrachtáin ‘descendant of Arrachtán’, a personal name from a diminutive of arrachtach ‘mighty’, ‘powerful’.Irish (County Kerry) : adopted as an Anglicized form of Gaelic Ó hIongardail, later Ó hUrdáil, ‘descendant of Iongardal’.Irish : reduced Anglicized form of Gaelic Ó hOireachtaigh ‘descendant of Oireachtach’, a byname meaning ‘member of the assembly’ or ‘frequenting assemblies’.

    Harrington

  • Ionessa
  • Girl/Female

    Greek

    Ionessa

    Amethyst.

    Ionessa

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