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Chemical compound
Phosphanides are chemicals containing the [PH2]− anion. This is also known as the phosphino anion or phosphido ligand. The IUPAC name can also be dihydridophosphate(1−)
Phosphanide
Anion derived from deprotonation of ammonia
Ammonia Structure Molecular shape Bent Related compounds Other anions Phosphanide Arsinide Imide Nitride Nitridohydride Related isoelectronic water, fluoronium
Azanide
Chemical compound
condenses to a colorless liquid. It can be produced by methylation of phosphanide salts: KPH2 + MeI → MePH2 + KI The compound exhibits the properties characteristic
Methylphosphine
Ion containing two or more atoms
Hydrogenphosphate HPO42− Hydrogenperoxymonophosphate HPO52− Protonated twice Phosphanide H2P− Phosphinate or hypophosphite H2PO2− Hydrogenphosphite H2PO3− Dihydrogenphosphate
Polyatomic_ion
Chemical compound hydrogen phosphide
exchange proceeds via a phosphonium (PH+4) ion in acidic solutions and via phosphanide (PH−2) at high pH, with equilibrium constants Kb = 4×10−28 and Ka = 41
Phosphine
Chemical compound
Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium
Sodium bis(trimethylsilyl)amide
Sodium_bis(trimethylsilyl)amide
Chemical compound
compounds Related compounds Arsanylium AsH+2 Arsine AsH3 Azanide NH−2 Phosphanide PH−2 Except where otherwise noted, data are given for materials in their
Arsinide
selenium analog of hydroxide Azanide, a nitrogen analog of hydroxide Phosphanide, a phosphorus analog of hydroxide and azanide Arsanide, an arsenic analog
Alkali_hydroxide
Topics referred to by the same term
phph PH2, a postcode in Perth, Scotland, see PH postcode area PH2− the phosphanide ion in inorganic chemistry -PH2 the phosphanyl group in organic chemistry
Ph2
Chemical compound
through sequential phosphanide/phosphine displacement of 1,3-alkyl dihalides or sulfonate esters (OTf, OTs, OMs, etc.). The phosphanide source is commonly
Phosphetane
Class of compounds
(2010-05-17). "Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide Ligand". Inorganic Chemistry. 49 (10): 4698–4707. doi:10.1021/ic1003534
Diphosphagermylene
Chemical compound
structure of potassium phosphide (K3P) Names Other names Tripotassium;phosphanide Tripotassium;phosphorus(3-) Tripotassium phosphide Identifiers CAS Number
Potassium_phosphide
phosphido is often a bridging ligand. The -PH2 ion or ligand is also called phosphanide or phosphido ligand. One can generate transition-metal phosphido complexes
Transition metal phosphido complexes
Transition_metal_phosphido_complexes
Group of chemicals
Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium
Metal bis(trimethylsilyl)amides
Metal_bis(trimethylsilyl)amides
the scheme on the left, it is also possible to use pre-formed lithium phosphanides Ar'P(H)Li as both a phosphorus source and a base. However, the latter
Phosphasilene
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