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Chemical compound
Selectfluor, a trademark of Air Products and Chemicals, is a reagent in chemistry that is used as a fluorine donor. This compound is a derivative of the
Selectfluor
Chemical compound
reactions of aldehydes and unsaturated ketones and aldehydes. The reagent Selectfluor is derived by alkylation of DABCO with dichloromethane following by treatment
DABCO
Fluorine reaction
N-fluoro-o-benzenedisulfonimide (NFOBS), N-fluorobenzenesulfonimide (NFSI), and Selectfluor. The mechanism of electrophilic fluorination remains controversial. At
Electrophilic_fluorination
Chemical reaction which adds one or more halogen elements to a compound
electrochemical, or enzymatic oxidation. Common oxidants include PIDA, Selectfluor, molecular oxygen, and hydrogen peroxide. DMSO has also been shown to
Halogenation
Catalysis in enantioselective synthesis
chiral counteranion. In the example below, the fluorinating reagent Selectfluor exhibits extremely limited solubility in nonpolar solvents and is therefore
Asymmetric counteranion directed catalysis
Asymmetric_counteranion_directed_catalysis
Chemical reaction
over several hours to give the quaternized product (see the article on Selectfluor). Due to steric hindrance and unfavorable electronic properties, chloroform
Menshutkin_reaction
Chemical reaction in which halogen substituents are added to aromatic molecules
fluorination is possible with F2/N2 (10%), XeF2, or N-F reagents like Selectfluor, these methods are seldom used, due to the formation of isomeric mixtures
Electrophilic_halogenation
Chemical compound
salts, useful as fluorine transfer reagents in organic synthesis (e.g., Selectfluor), from the corresponding tertiary amine: [R–+N(CH2CH2)3N:][BF− 4] + XeF2
Xenon_difluoride
Chemical compound
cation ([C5H5NF]+) and the triflate anion. Related reagents include Selectfluor, which is also an N-fluorinated salt. N-Fluoropyridinium cations are
N-Fluoropyridinium_triflate
Chemical compound
7F. 1-Fluoronaphthalene can be obtained by reacting naphthalene with Selectfluor. 1-Fluoronaphthalene is a colorless, combustible liquid, which is insoluble
1-Fluoronaphthalene
system to free radical hydrofluorination of unactivated alkenes using Selectfluor reagent as a source of fluorine and resulting in exclusive Markovnikov
Metal-hydride hydrogen atom transfer
Metal-hydride_hydrogen_atom_transfer
Anion
Fe(C5H5)+2, and other cationic metallocenes. [Ni(CH3CH2OH)6](BF4)2. Selectfluor, a fluorination agent, and other N−F electrophilic fluorine sources.
Tetrafluoroborate
arylsilanes, and act as an atomic fluorine source to furnish aryl fluorides. Selectfluor and N-fluorobenzenesulfonimide (NFSI) are traditionally used as electrophilic
Radical_fluorination
Index of chemical compounds with the same name
various other N-fluorinated pyridinium compounds, as well as Accufluor and Selectfluor. Furthermore, allyl fluorides can be produced by forming a double bond
Allyl_halide
supports a concerted SEAr-type pathway. Aryl germanes are stable against selectfluor. The electrophilic fluorination will selectively place at the –Bu3Sn
Organogermanium compounds in cross-coupling reactions
Organogermanium_compounds_in_cross-coupling_reactions
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