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Class of organotin(II) compounds
Stannylenes (R2Sn:) are a class of organotin(II) compounds that are analogues of carbene. Unlike carbene, which usually has a triplet ground state, stannylenes
Stannylene
Class of positively-charged molecules
germane) Unstable derivative known of R3Ge+. stannonium, SnH+3 (protonated stannylene, SnH2) (not protonated stannane SnH4) stable at cryogenic conditions.
Onium_ion
Chemical element with atomic number 50 (Sn)
attributed to the "inert pair effect". Organotin(II) compounds include both stannylenes (formula: R2Sn, as seen for singlet carbenes) and distannylenes (R4Sn2)
Tin
Class of organophosphorus compounds
favors reactivity at this site. In 2024, a carbodiphosphorane-stabilized stannylene, a heavier analogue of a carbene, was reported and its ability to perform
Carbodiphosphoranes
Organotin compound
catalyze a [2+2+1] cycloaddition between two acetylene molecules and a stannylene SnR2 to give the corresponding stannole. 1λ2-Stannole has formula C4H4Sn
Stannole
Examples include (pentamethylcyclopentadienyl)aluminium(I) (Al(I)), stannylenes (Sn(II)), and diphosphenes (P(I)). Thus organic derivatives of the electropositive
Main group organometallic chemistry
Main_group_organometallic_chemistry
British Inorganic Chemist
of boryl- and aluminyl anions, in addition to acyclic silylenes and stannylenes. In addition to his research articles, Aldridge co-authored a book on
Simon_Aldridge
Principle in chemical kinetics
the synthesis of carbohydrates and other polyhydroxylated compounds. Stannylene acetals have been used to efficiently achieve this transformation. The
Curtin–Hammett_principle
Organic Chemistry involving Germanium
"Synthesis and Structure of Stable Tri-tert-butylgermyl-Substituted Stannylene and Germylene". Organometallics. 20 (22): 4460–4462. doi:10.1021/om010591h
Organogermanium_chemistry
Divalent organolead(II) analogues of carbenes
decreasing dimerization energy down Group 14, while monohalogenated stannylenes and plumbylenes dimerize via the halogen-bridging mode, monohalogenated
Plumbylene
Group of atoms introduced into a compound to prevent subsequent reactions
regiospecific benzylation and allylation of polyhydroxy-compounds via their stannylene derivatives in non-polar solvents", in: J. Chem. Soc., Perkin Trans. 1
Protecting_group
Chemical compound
Wass, Duncan F. (2011-03-21). "Coordination Chemistry of N-Heterocyclic Stannylenes: A Combined Synthetic and Mössbauer Spectroscopy Study". Inorganic Chemistry
Pentacarbonyl(tetrahydrofuran)tungsten
Pentacarbonyl(tetrahydrofuran)tungsten
Group of carbenes
are silylenes, R2Si:, germylenes R2Ge: (example diphosphagermylene), stannylenes R2Sn: and plumbylenes R2Pb:, collectively known as metallylenes and regarded
Carbene_analog
Class of germanium (II) compounds
catecholborane to regenerate the germylene compound. Carbene analogs Silylene Stannylene Mizuhata, Yoshiyuki; Sasamori, Takahiro; Tokitoh, Norihiro (2009). "Stable
Germylene
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