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Transmission of electronic effects through a system of conjugated chemical bonds
In organic chemistry, vinylogy is the transmission of electronic effects through a conjugated organic bonding system. The concept was introduced in 1926
Vinylogy
System of connected p-orbitals with delocalized electrons in a molecule
engage in spiroconjugation or in homoconjugation across the spiro atom. Vinylogy is the extension of a functional group through a conjugated organic bonding
Conjugated_system
Organic compound with a C=C–OH group
in great quantities during quenching. Enols can be stabilized through vinylogy. Thus, very stable enols are phenols. In compounds with two (or more) carbonyls
Enol
German chemist (1865–1921)
State Library Düsseldorf FusoN, Reynold C. (1935-02-01). "The Principle of Vinylogy". Chemical Reviews. 16 (1): 1–27. doi:10.1021/cr60053a001. ISSN 0009-2665
Emil_Knoevenagel
Organic anion formed by deprotonating a carbonyl (>C=O) compound
Andrea; Zanardi, Franca (2020). "New Developments of the Principle of Vinylogy as Applied to π-Extended Enolate-Type Donor Systems". Chemical Reviews
Enolate
American chemist (1895–1979)
Fuson’s research interests were wide-ranging. He enunciated the principle of vinylogy which is now taught in terms of resonance in valence bond theory, elucidated
Reynold_C._Fuson
Type of carbene demonstrating particular stability
bis(diisopropylamino)cyclopropenylidene, in which the amines are connected through vinylogy. In 2000, Bertrand obtained a moderately stable (amino)(aryl)carbene with
Persistent_carbene
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