AI & ChatGPT searches , social queries for HYDROPEROXIDE
Search references for HYDROPEROXIDE. Phrases containing HYDROPEROXIDE
See searches and references containing HYDROPEROXIDE!
Search references for HYDROPEROXIDE. Phrases containing HYDROPEROXIDE
See searches and references containing HYDROPEROXIDE!HYDROPEROXIDE
Class of chemical compounds
Hydroperoxides or peroxols are compounds of the form ROOH, where R stands for any group, typically organic, which contain the hydroperoxy functional group
Hydroperoxide
Chemical compound
tert-Butyl hydroperoxide (tBuOOH) is the organic compound with the formula (CH3)3COOH. It is one of the most widely used hydroperoxides in a variety of
Tert-Butyl_hydroperoxide
Chemical compound
Diethyl ether hydroperoxide is the organic compound with the formula C2H5OCH(OOH)CH3. It is a colorless liquid. Diethyl ether hydroperoxide and its condensation
Diethyl_ether_peroxide
Aromatic organic chemical compound
Cumene hydroperoxide is the organic compound with the formula C6H5C(CH3)2OOH; this oily liquid is classified as an organic hydroperoxide. Products of
Cumene_hydroperoxide
Chemical compound
organic hydroperoxide, methyl hydroperoxide is an intermediate in the oxidation of methane. When condensed or in concentrated form methyl hydroperoxide is
Methyl_hydroperoxide
Chemical compound
Paramenthane hydroperoxide (PMHP) is an organic peroxide with a distinctive odor. It is used on an industrial scale as a polymerization initiator for
Paramenthane_hydroperoxide
Chemical compound
Ethylbenzene hydroperoxide is the organic compound with the formula C6H5CH(O2H)CH3. A colorless liquid, EBHP is a common hydroperoxide. It has been used
Ethylbenzene_hydroperoxide
Index of enzymes associated with the same name
8-hydroperoxide isomerase may refer to: 9,12-octadecadienoate 8-hydroperoxide 8R-isomerase, an enzyme 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase
8-hydroperoxide_isomerase
Reaction(s) leading to production of (phospho)lipid peroxides
oxidative degradation of lipids, resulting in the formation of peroxide and hydroperoxide derivatives. It occurs when free radicals, specifically reactive oxygen
Lipid_peroxidation
Chemical compound
Triphenylmethyl hydroperoxide is the organic compound with the formula (C6H5)3COOH. It is the hydroperoxide (OOH-containing) derivative of triphenylmethane
Triphenylmethyl_hydroperoxide
Chemical compound
Ethyl hydroperoxide is the organic compound with the formula CH3CH2OOH. It is a colorless liquid that is miscible with water and diethyl ether. Ethyl
Ethyl_hydroperoxide
Class of enzymes
Hydroperoxide lyases are enzymes that catalyze the cleavage of C-C bonds in the hydroperoxides of fatty acids. They belong to the cytochrome P450 enzyme
Hydroperoxide_lyase
The enzyme hydroperoxide dehydratase (EC 4.2.1.92) catalyzes the chemical reaction (9Z,11E,14Z)-(13S)-hydroperoxyoctadeca-9,11,14-trienoate ⇌ {\displaystyle
Hydroperoxide_dehydratase
Chemical compound
Cyclohexyl hydroperoxide (CHHP) is an organic hydroperoxide that is typically used to assist in industrially producing cyclohexanol and cyclohexanone.
Cyclohexyl_hydroperoxide
Organic compounds of the form R–O–O–R′
(R−O−O−R′). If the R′ is hydrogen, the compounds are called organic hydroperoxides. The O−O bond of peroxides easily breaks, producing free radicals of
Organic_peroxides
Terpene hydrocarbon
F.; et al. (2017). "Contact sensitization to limonene and linalool hydroperoxides in Spain: A GEIDAC prospective study" (PDF). Contact Dermatitis. 76
Limonene
Organic reaction
reaction is the reaction of singlet oxygen with alkenes to yield hydroperoxides. The hydroperoxides can be reduced to allylic alcohols or eliminate to form unsaturated
Schenck_ene_reaction
Chemical compound
The hydroperoxyl radical, also known as the hydrogen superoxide, is the protonated form of superoxide with the chemical formula HO2, also written HOO•
Hydroperoxyl
Chemical compound
Ethaneperoxoic acid Other names Peroxyacetic acid Acetic peroxide Acetyl hydroperoxide Proxitane Percidine Identifiers CAS Number 79-21-0 Y 3D model (JSmol)
Peracetic_acid
Substance that can explode
Chlorine oxides Copper(I) acetylide Copper(II) azide Cumene hydroperoxide Cycloprop(-2-)enyl nitrate (CXP or CPN) Cyanogen azide Cyanuric triazide
Explosive
Chemical compound
com. Retrieved 2018-07-26. KenjiMatsui (2006). "Green leaf volatiles: hydroperoxide lyase pathway of oxylipin metabolism". Current Opinion in Plant Biology
Cis-3-Hexenal
Industrial process
formations of cumene hydroperoxides. A pressure of 5 atm is used to ensure that the unstable peroxide is kept in liquid state. Cumene hydroperoxide undergoes a
Cumene_process
Family of antioxidant enzymes
is the reduction of peroxides, specifically hydrogen peroxide, alkyl hydroperoxides, and peroxynitrite. Prxs were historically divided into three (mechanistic)
Peroxiredoxin
Class of enzymes
9,12-octadecadienoate 8-hydroperoxide 8S-isomerase (EC 5.4.4.6, 8-hydroperoxide isomerase, (8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate mutase ((7S
9,12-octadecadienoate 8-hydroperoxide 8S-isomerase
9,12-octadecadienoate_8-hydroperoxide_8S-isomerase
Isomer/derivative of butane
loop reactor for this purpose. Isobutane is oxidized to tert-butyl hydroperoxide, which is subsequently reacted with propylene to yield propylene oxide
Isobutane
Phenomenon in chemistry
an H atom from the polymer chain to give a hydroperoxide (POOH) and a fresh macroradical. Hydroperoxides readily undergo photolysis to give an alkoxyl
Photo-oxidation_of_polymers
Organic compound
produced as a pure compound on an industrial scale is converted to cumene hydroperoxide, which is an intermediate in the synthesis of other industrially important
Cumene
Chemical compound
ethylbenzene is treated with oxygen to form the ethylbenzene hydroperoxide. This hydroperoxide is then used to oxidize propylene to propylene oxide, which
Styrene
P450BS, P450SPalpha) is an enzyme with systematic name fatty acid:hydroperoxide oxidoreductase (RH-hydroxylating). This enzyme catalyses the following
Fatty-acid_peroxygenase
phospholipid-hydroperoxide glutathione peroxidase (EC 1.11.1.12) is an enzyme that catalyzes the chemical reaction 2 glutathione + a lipid hydroperoxide ⇌ {\displaystyle
Phospholipid-hydroperoxide glutathione peroxidase
Phospholipid-hydroperoxide_glutathione_peroxidase
Chemical compound
by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide. Unlike other isomers of butanol
Tert-Butyl_alcohol
Chemical compound
Methyl ethyl ketone peroxide (MEKP) is an organic peroxide with the formula [(CH3)(C2H5)C(O2H)]2O2. MEKP is a colorless oily liquid. It is widely used
Methyl_ethyl_ketone_peroxide
Class of enzymes
12-octadecadienoate 8-hydroperoxide 8R-isomerase (EC 5.4.4.5, 5,8-LDS (bifunctional enzyme), 5,8-linoleate diol synthase (bifunctional enzyme), 8-hydroperoxide isomerase
9,12-octadecadienoate 8-hydroperoxide 8R-isomerase
9,12-octadecadienoate_8-hydroperoxide_8R-isomerase
Chemical compound
protection. Reaction with hydrogen peroxide gives an unusually stable hydroperoxide, Ph3COOH. As a derivative of methanol, triphenylmethanol is expected
Triphenylmethanol
Organic compound (C6H5OH)
oxidized to a hydroperoxide, akin to the production of cumene hydroperoxide. Via the Hock rearrangement, cyclohexylbenzene hydroperoxide cleaves to give
Phenol
Chemical compound
lipoxygenase, followed by cleavage of the resulting hydroperoxide with the help of a hydroperoxide lyase. This reaction takes place in cheese and is used
1-Octen-3-ol
Mammalian protein found in Homo sapiens
(GPX1–8). GPX4 catalyzes the reduction of hydrogen peroxide, organic hydroperoxides, and lipid peroxides at the expense of reduced glutathione and functions
Glutathione_peroxidase_4
Chemical compound
oxidized to a hydroperoxide, akin to the production of cumene hydroperoxide. Via the Hock rearrangement, cyclohexylbenzene hydroperoxide cleaves to give
Cyclohexylbenzene
Oil that hardens after exposure to air
of the double bonds within the unsaturated fatty acid. The resulting hydroperoxides are susceptible to crosslinking reactions. Bonds form between the fatty
Drying_oil
Enzyme family protecting the organism from oxidative damages
The biochemical function of glutathione peroxidase is to reduce lipid hydroperoxides to their corresponding alcohols and to reduce free hydrogen peroxide
Glutathione_peroxidase
Stabilizer added to polymeric materials
antioxidants act to remove organic hydroperoxides (ROOH) formed by the action of primary antioxidants. Hydroperoxides are less reactive than radical species
Polymer_stabilizer
Protein family
catalyze the reaction Polyunsaturated fatty acid + O2 → fatty acid hydroperoxide in four steps: the rate-limiting step of hydrogen abstraction from a
Lipoxygenase
Autoxidation or hydrolysis of fats and oils
the lipoxygenase article shows that if a hydroperoxide lyase enzyme is present, it can cleave the hydroperoxide to yield short-chain fatty acids and dicarboxylic
Rancidification
Industrial Production Process
their theory, as the first step a secondary hydroperoxide is formed. The assumption that this hydroperoxide is then radically decomposed was confirmed
Paraffin_oxidation
Chemical compound
quantities. Acetophenone is also generated from ethylbenzene hydroperoxide. Ethylbenzene hydroperoxide is primarily converted to 1-phenylethanol (α-methylbenzyl
Acetophenone
Class of chemical compounds
PMC 5789745. PMID 29378628. Matsui K (2006). "Green leaf volatiles: hydroperoxide lyase pathway of oxylipin metabolism". Current Opinion in Plant Biology
Green_leaf_volatiles
Organic compounds with a carbon-carbon-oxygen ring
spontaneous decomposition or even combustion. Both t-butyl hydroperoxide and ethylbenzene hydroperoxide can be used as oxygen sources during propylene oxidation
Epoxide
Highly reactive molecules formed from diatomic oxygen (O2)
oxygen (O2), water, and hydrogen peroxide. Some prominent ROS are the hydroperoxide radical or hydroperoxyl (HO2), superoxide (O2−), the hydroxyl radical
Reactive_oxygen_species
Chemical process by which polymeric materials are hardened
step, the diene undergoes autoxidation to give a hydroperoxide. In the second step, the hydroperoxide combines with another unsaturated side chain to generate
Curing_(chemistry)
Flavoprotein
hydroxide is transferred to the substrate from the hydroperoxide flavin, flavin-C4a-hydroperoxide, via an electrophilic aromatic substitution-type reaction
4-hydroxybenzoate 3-monooxygenase
4-hydroxybenzoate_3-monooxygenase
Chemical compound
Arachidonic acid 5-hydroperoxide (5-hydroperoxyeicosatetraenoic acid, 5-HPETE) is an intermediate in the metabolism of arachidonic acid by the ALOX5 enzyme
Arachidonic acid 5-hydroperoxide
Arachidonic_acid_5-hydroperoxide
Chemical compound
production of adipic acid. The oxidation involves radicals and the hydroperoxide C6H11O2H as an intermediate. In some cases, purified cyclohexanol, obtained
Cyclohexanone
Superacid system prepared from a Brønsted and a Lewis superacid
" Magic acid catalyzes cleavage-rearrangement reactions of tertiary hydroperoxides and tertiary alcohols. The nature of the experiments used to determine
Magic_acid
Chemical reaction
primary and secondary allylic alcohols. The oxidizing agent is tert-butyl hydroperoxide. The method relies on a catalyst formed from titanium tetra(isopropoxide)
Sharpless_epoxidation
Spontaneous oxidation by oxygen at normal temperature
radical chain reaction, where the addition of oxygen gives rise to hydroperoxides and their associated peroxy radicals (ROO•). Typically, an induction
Autoxidation
Organic compounds made of alkyl/aryl groups bound to oxygen (R–O–R')
oxygen, ethers tend to form explosive peroxides, such as diethyl ether hydroperoxide. The reaction is accelerated by light, metal catalysts, and aldehydes
Ether
Chemical compound
NaOH → CH3OOCH3 + Na2SO4 + 2 H2O Another approach includes treating hydroperoxides with alkylating agents, which can produce dimethyl peroxide among other
Dimethyl_peroxide
Organic redox reaction
Dakin. The Dakin oxidation starts with (1) nucleophilic addition of a hydroperoxide ion to the carbonyl carbon, forming a (2) tetrahedral intermediate.
Dakin_oxidation
Chemical compounds with the structure R–O–O–R'
Types of peroxides, from top to bottom: peroxide ion, organic peroxide, hydroperoxide, peracid. The peroxide group is marked in blue. R, R1 and R2 mark hydrocarbon
Peroxide
Chemical compound
industrially beginning with photooxygenation of citronellol to give the allyl hydroperoxide which is then reduced with sodium sulfite to provide the diol. Ring-closure
Rose_oxide
Peroxide-decomposing enzyme
substrate is hydrogen peroxide, but others are more active with organic hydroperoxides such as lipid peroxides. Peroxidases can contain a heme cofactor in
Peroxidase
Enzyme in humans
Nakamura H, Yodoi J, et al. (October 2002). "A comparative study on the hydroperoxide and thiol specificity of the glutathione peroxidase family and selenoprotein
Glutathione_peroxidase_3
Chemical compound
the acylation of tert-butyl hydroperoxide with benzoyl chloride. In the reaction a large excess of tert-butyl hydroperoxide is used and the hydrogen chloride
Tert-Butyl_peroxybenzoate
Numbers, classes, and proper shipping names allocated to dangerous goods
longer in use) tert-Butyl hydroperoxide (UN No. no longer in use) UN 2093 ? (UN No. no longer in use) tert-Butyl hydroperoxide (UN No. no longer in use)
List of UN numbers 2001 to 2100
List_of_UN_numbers_2001_to_2100
Chemical compound
Methaneperoxoic acid Other names Performic acid Hydroperoxyformaldehyde Formyl hydroperoxide Permethanoic acid Peroxyformic acid Identifiers CAS Number 107-32-4 Y
Performic_acid
Chemical compound
as a catalyst for the epoxidation of allylic alcohols by tert-butyl hydroperoxide (TBHP). The VO(acac)2–TBHP system exclusively epoxidizes geraniol at
Vanadyl_acetylacetonate
production of propylene oxide by oxidation of propylene with tert-butyl hydroperoxide. The reaction requires metal catalysts, which typically contain molybdenum:
Halcon_process
Chemical compound
sodium salt of trifluoromethanesulfinic acid. Together with t-butyl hydroperoxide, an oxidant, this compound was found to be a suitable reagent for introducing
Sodium trifluoromethanesulfinate
Sodium_trifluoromethanesulfinate
Species of flowering plant
(2000). "Protective effect of Hibiscus anthocyanins against tert-butyl hydroperoxide-induced hepatic toxicity in rats". Food and Chemical Toxicology. 38
Roselle_(plant)
Chemical compound
CH3CHCH2O + ROH The process is practiced with four hydroperoxides: In the Halcon process, t-Butyl hydroperoxide derived from oxygenation of isobutane, which
Propylene_oxide
Inflammatory disease involving a buildup of lesions in the walls of arteries
antioxidant systems, and accumulated significant amounts of phospholipid hydroperoxide in their blood, livers and kidneys. Rancid fats and oils taste very
Atherosclerosis
Chemical compound
isomers of pentyl alcohol. Neopentyl alcohol can be prepared from the hydroperoxide of diisobutylene. It can also be prepared by the reduction of trimethylacetic
Neopentyl_alcohol
Group of atoms giving a molecule characteristic properties
Ethyl butyrate (Ethyl butanoate) Hydroperoxide Hydroperoxy ROOH hydroperoxy- alkyl hydroperoxide tert-Butyl hydroperoxide Peroxide Peroxy ROOR′ peroxy- alkyl
Functional_group
Chemical compound
compound reacts with air to afford the bis(hydroperoxide), which is structurally similar to cumene hydroperoxide and rearranges in acid to give acetone and
Hydroquinone
Inherited neurodegenerative disorder
cell death characterized by the iron-dependent accumulation of lipid hydroperoxides to lethal levels. ALOX5-mediated ferroptosis acts as a cell death pathway
Huntington's_disease
Chemical compound
hydroperoxide, which rearranges via hydroxycyclodecanone to cyclodecenone, a precursor to sebacic acid. Decalin easily forms explosive hydroperoxides
Decalin
Organic chemical compound
common laboratory aprotic solvent. It is susceptible to the formation of hydroperoxides. A cytochrome P450 enzyme is proposed to metabolize diethyl ether. Diethyl
Diethyl_ether
Chemical compounds in which hydroxyl group is attached directly to an aromatic ring
carbonate in an acetonitrile/water mixture to a para-peroxyquinole. This hydroperoxide is reduced to the quinole with sodium thiosulfate. Phenols are oxidized
Phenols
Chemical compound
from terpinolene (1) via photooxygenation, reduction of the resulting hydroperoxide (2), and selective hydrogenation of the terminal double bond in 3. "Tea
Terpinen-4-ol
fungus Gaeumannomyces graminis: stereochemistry of dioxygenase and hydroperoxide isomerase reactions". Archives of Biochemistry and Biophysics. 309 (1):
Linoleate_8R-lipoxygenase
Biochemical processes which introduce C=O groups into proteins
(ROS) attacking the protein side chain. ROS species include hydroperoxide or lipic hydroperoxides. Protein carbonylation is of interest because of its association
Protein_carbonylation
Free radical toxicity
Extremely reactive, will attack most cellular components ROOH, organic hydroperoxide Formed by radical reactions with cellular components such as lipids
Oxidative_stress
soybean peroxygenase) is an enzyme with systematic name substrate:hydroperoxide oxidoreductase (RH-hydroxylating or epoxidising). This enzyme catalyses
Plant_seed_peroxygenase
Mammalian protein found in Homo sapiens
monooxygenase form flavin hydroperoxides at the enzyme active site, which then transfer the terminal oxygen atom of the hydroperoxide to the substrate. Squalene
Squalene_monooxygenase
Chemical group (–CH2–CH=CH2)
(O2), starting with lipid peroxidation. Products include fatty acid hydroperoxides, epoxy-hydroxy polyunsaturated fatty acids, jasmonates, divinylether
Allyl_group
Unstable oxoacid of sulfur
discharge through a neon, H2, SO2 mixture. This also yields some sulfhydryl hydroperoxide. Sulfoxylic acid is an isomer of sulfinic acid, which has a hydrogen
Sulfoxylic_acid
Essential oil of the bitter orange blossom
Jedrzejewska-Jurga K, Krakowski A, Niklasson B (2016). "Gallates, as well as hydroperoxides of limonene and linalool, are more frequent and relevant sensitizers
Neroli
Class of aromatic organic chemicals found in plants
terpenoids are converted into various species, such as aldehydes, hydroperoxides, organic nitrates, and epoxides by short-lived free radicals (like the
Terpenoid
Chemical compound
4-tetrahydronaphthalene tends to autoxidize and gradually forms the 1-hydroperoxide with atmospheric oxygen. The heavy metal ion catalyzed air oxidation
1-Tetralone
Atom, molecule, or ion that has an unpaired valence electron; typically highly reactive
radical (HOO•) are formed. These then react further to give organic hydroperoxides that break up into hydroxyl radicals (HO•).[citation needed] Many polymerization
Radical_(chemistry)
System for naming organic chemical compounds
hydroxy- sulfanyl- selanyl- tellanyl- -ol -thiol -selenol -tellurol 8 Hydroperoxides Peroxols Thioperoxols (Sulfenic acid) Dithioperoxols −OOH −SOH −SSH
IUPAC nomenclature of organic chemistry
IUPAC_nomenclature_of_organic_chemistry
Chemical compound
Peroxybenzoic acid Perbenzoic acid Benzoperoxoic acid Hydroxy benzoate Benzoyl hydroperoxide Identifiers CAS Number 93-59-4 Y 3D model (JSmol) Interactive image
Peroxybenzoic_acid
Redox-active coenzyme
reacts with molecular oxygen to form the flavin-C(4a)-hydroperoxide. The flavin hydroperoxide quickly hydroxylates pOHB, and then eliminates water to
Flavin_adenine_dinucleotide
Chemical compound
conditions, the main oxidation products are pinene oxide, verbenyl hydroperoxide, verbenol and verbenone. Monoterpenes, of which α-pinene is one of the
Α-Pinene
Inflammation of the skin due to contact with an allergen
(2002). "Allergy to fragrance mix". DermNetNZ. "Contact allergy to hydroperoxides of limonene and linalool - DermNet". DermNet®. October 26, 2023. Retrieved
Allergic_contact_dermatitis
Chemical compound
of atmospheric oxygen to the C2 carbon of RuBP forming a high energy hydroperoxide intermediate that decomposes into 2-phosphoglycolate and 3-phosphoglycerate
2-Phosphoglycolate
Organic compound consisting entirely of hydrogen and carbon
process, which is called autoxidation, begins with the formation of hydroperoxides (ROOH). Combustion of hydrocarbons is currently the main source of the
Hydrocarbon
Class of biochemical compounds
Momordica charantia and their cytoprotective activity in tert-butyl hydroperoxide-induced hepatotoxicity of HepG2 cells". Chemical & Pharmaceutical Bulletin
Cucurbitacin
Polyatomic ion (N(C4H9)4, charge +1)
"Tetrabutylammonium Iodide Catalyzed Synthesis of Allylic Ester with tert-Butyl Hydroperoxide as an Oxidant". Organic Letters. 14 (13): 3384–3387. doi:10.1021/ol3013606
Tetrabutylammonium
Chemical compound
formed from α-linolenic acid. Such reactions are typically catalyzed by hydroperoxide lyases. 2-Nonenal - Structurally related, aroma of cucumber 6-Nonenal
Trans,cis-2,6-Nonadienal
HYDROPEROXIDE
HYDROPEROXIDE
HYDROPEROXIDE
HYDROPEROXIDE
Girl/Female
Arabic
Universal
Girl/Female
Indian
Glittering, Shining, Thin
Girl/Female
American, British, English, Scandinavian
Beverage Brandy; Variant of the Beverage Brandy Used as a Given Name; Brandy; After Dinner Drink
Girl/Female
Welsh
Omen.
Biblical
fortified; raised
Female
Egyptian
, a priestess of Amen Ra.
Girl/Female
Indian, Tamil
Sings and Dance; Loving Beauty
Boy/Male
Arabic, Muslim
Servant of God
Boy/Male
Indian, Tamil
King of Heart
Girl/Female
Assamese, Gujarati, Hindu, Indian, Kannada, Malayalam, Marathi, Mythological, Sanskrit, Tamil, Telugu
Brought Up by Birds
HYDROPEROXIDE
HYDROPEROXIDE
HYDROPEROXIDE
HYDROPEROXIDE
HYDROPEROXIDE