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Polymers with polar and nonpolar functionalities
functionalized polyolefin can be categorized into four main groups: randomly functionalized polyolefins, end-functionalized polyolefins, block polyolefins, and
Functionalized_polyolefins
Family of related polymers
usually not considered polyolefins. Polymers derived from polar monomers are also usually excluded from this classification. Polyolefins are the foundations
Polyolefin
Chemical compound
(DGEBA), glycidyl methacrylate is instead used to provide epoxy functionalization to polyolefins and other acrylate resins. Glycidyl methacrylate is produced
Glycidyl_methacrylate
Metallocenes. Reactivity, Scope, Reaction Mechanism, and Routes to Functionalized Polyolefins". Journal of the American Chemical Society. 118 (34): 7900–7913
Β-Carbon_elimination
difficult to be functionalized, recent advances in insertion polymerization and post-polymerization can be used to produce telechelic polyolefins. Telechelic
Telechelic_polymer
Very large molecule
macromolecules are biopolymers (RNA and DNA, proteins, and carbohydrates), polyolefins (polyethylene) and polyamides (nylon). Many macromolecules are synthetic
Macromolecule
Application of a gas flame to the surface of a material
application of a gas flame to the surface of a material to improve adhesion. Polyolefins, especially polyethylene and polypropylene bond poorly, because they
Flame_treatment
Phenomenon in chemistry
the others, which include polystyrene, polyvinyl chloride (PVC) and polyolefins like polypropylene (PP) and polyethylene (PE) are all highly susceptible
Photo-oxidation_of_polymers
Most common thermoplastic polymer
and rubber industry. When chlorinated polyethylene is added to other polyolefins, it reduces the flammability. Chlorosulfonated PE (CSM) is used as starting
Polyethylene
Form of thermoplastic adhesive
polyamides. Polyolefins have low surface energy and provide good wetting of most metals and polymers. Metallocene-catalyst-synthesised polyolefins have a narrow
Hot-melt_adhesive
manufacturing, and application of coatings. A polymeric material can be functionalized by the addition of small moieties, oligomers, and even other polymers
Polymeric_surface
American polymer chemist
Caltech, Coates worked on ring-closing metathesis reactions to functionalize polyolefins, and supramolecular phenyl-perfluorophenyl pi-stacking interactions
Geoffrey_W._Coates
Chemical reaction to form polymer chains
via a variety of reaction mechanisms that vary in complexity due to the functional groups present in the reactants and their inherent steric effects. In
Polymerization
Chemical compound
Even though HALS are extremely effective in polyethylene and other polyolefins, and polyurethane, they are ineffective in polyvinyl chloride (PVC).
Hindered amine light stabilizers
Hindered_amine_light_stabilizers
Type of chemical synthesis
various methods of radical polymerization, such as ring-opening and polyolefins. This includes free-radical polymerization, such as the development of
Automated_synthesis
German chemical company
original on 10 May 2015. Retrieved 7 May 2015. "BASF completes sale of polyolefins catalyst business to W.R. Grace". BIC Magazine. 1 July 2016. Retrieved
BASF
Equation in polymer science
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Mark–Houwink_equation
ExxonMobil materials scientist
100 patents. His inventions include low permeability nanocomposites, functionalized elastomer nanocomposites, and oriented thermoplastic vulcanizates 2000
Andy_H._Tsou
Type of plastic
silanes (e.g. trimethoxyvinylsilane) polyethylene can initially be Si-functionalized by irradiation or by a small amount of a peroxide. Later Si-OH groups
Cross-linked_polyethylene
Chemical group (>N–C(=S)–S–)
Zinc dithiocarbamates are used to modify the crosslinking of certain polyolefins with sulfur, a process called vulcanization. They are used as ligands
Dithiocarbamate
Material of a wide range of synthetic or semi-synthetic organic solids
polymer correlates with the presence of functional groups (esters, amides). Polyolefins, which lack functional groups, degrade very slowly, especially
Plastic
Catalyzed organic reactions that produce an organoboron compound
converted to a 1,3,5-organoborane compound and subsequently functionalized. Aromatic C–H functionalization was successfully incorporated in the total synthesis
Borylation
Polymer researcher and chemistry PhD
incorporating functional groups into polyolefins, combining polymerization methodologies to design novel polymer structures containing polyolefins. The group
Eva_Harth
Dutch multinational corporation
2002: Petrochemicals (hydrocarbons, polyethylenes, polypropylenes, polyolefins). 2001: Quinine and Cinchona Alcaloids to Buchler GmbH [de]. 2010: Ammonia
DSM_(company)
Cross-coupling reaction between boronic acid & an organohalide
combination is the Suzuki–Miyaura reaction. It is widely used to synthesize polyolefins, styrenes, and substituted biphenyls. The general scheme for the Suzuki
Suzuki_reaction
Collapse of a macromolecule from an expanded coil state to a collapsed globule state
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Coil–globule_transition
Critical temperature of miscibility in a mixture
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Upper critical solution temperature
Upper_critical_solution_temperature
Alteration in the polymer properties under the influence of environmental factors
bear functional groups the enzymes can 'recognise', such as ester or amide groups. Long-chain polymers with all-carbon backbones like polyolefins, polystyrene
Polymer_degradation
be deployable within the cloud. as a service Ugbolue, S.C.O. (2009). Polyolefin Fibres: Industrial and Medical Applications. Woodhead publishing in textiles
Monitoring_as_a_service
Temperature below which components of a mixture are miscible
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Lower critical solution temperature
Lower_critical_solution_temperature
Polymers that break down by bacterial decomposition
physical size, and the presence of specific microorganisms. Synthetic polyolefins (polyethylene, etc) are some of the least degradable. Depressed plastics
Biodegradable_polymer
Lattice model of polymer solutions
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Flory–Huggins_solution_theory
Reversible-deactivation radical polymerization
Synthesis of Well-Defined Functionalized Polymers via ATRP". Sigma-Aldrich. Retrieved 21 July 2010. <!- -Not stated- ->. "Use of Functional ATRP Initiators".
Atom transfer radical polymerization
Atom_transfer_radical_polymerization
Swiss specialty chemicals company
Minolta Inc, a Japanese technology company to efficiently colour match the polyolefin products easier and faster. In the same year, Clariant acquired Kel-Tech
Clariant
Chemical deactivation of a catalyst
desulfurization system is used. Ziegler-Natta catalysts for the production of polyolefins (e.g. polyethylene, polypropylene, etc.) are poisoned by water and oxygen
Catalyst_poisoning
Subfield of materials science concerned with polymers
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Polymer_science
Substance with high latent heat of melting or solidifying
solar-thermal conversion and storage materials by incorporating amino-functionalized single-walled carbon nanotubes into a polyethyleneglycol based polyurethane
Phase-change_material
Topological interaction between long polymer chains that constrains their motion
polymer is brittle. The difference between candle wax (low molecular weight polyolefin) and a polyethylene milk jug is largely a difference in entanglement density:
Chain_entanglement
Type of polymeric alloy
strips are co-extruded in multi-layer strips. Outer layers are a blend of polyolefins while the core layer is formed from a high performance polymer. The blend
Novel_polymeric_alloy
Soft water-rich polymer gel
ISBN 978-1-84973-561-2. Mehrban N, Zhu B, Tamagnini F, et al. (June 2015). "Functionalized α-Helical Peptide Hydrogels for Neural Tissue Engineering". ACS Biomaterials
Hydrogel
Japanese chemicals company
2001 : SDK merged with Showa Aluminum Corporation. Sept.2003 : Japan Polyolefins Co., Ltd. and Japan Polychem Corporation integrated the polyethylene
Resonac
Agents that emit light after excitation by light
analysis of cellular uptake of different sized polymers. Fluorescent polyolefins, such as fluorescent polyethylene, have been synthesized and explored
Fluorophore
Type of retail packaging
light, and moisture. EVOH is often used as an oxygen barrier, while polyolefins provide moisture resistance. Another application is modified atmosphere
Multilayered_packaging
Greek-American businessman and philanthropist
products business. In 1977, he was promoted to business manager of Dow's polyolefins division, and over the next decade, he moved up the corporate ranks,
William_S._Stavropoulos
Substance applied to items to slow burning or delay ignition
the maximum processing temperature of the polymers (typically used in polyolefins for wire and cable applications). A way to stop spreading of the flame
Flame_retardant
Packaging which results in improved sustainability
Facilities Ammala, Anne (2011). "An overview of degradable and biodegradable polyolefins". Progress in Polymer Science. 36 (8): 1015–1049. doi:10.1016/j.progpolymsci
Sustainable_packaging
Type of polymerization reaction mechanism
step-growth polymerization is a type of polymerization mechanism in which bi-functional or multifunctional monomers react to form first dimers, then trimers,
Step-growth_polymerization
British pharmaceutical scientist
also researched radiation-mediated grafting of hydrophilic polymers on polyolefin surfaces and complexes formed between linear polymers and hydrogels. His
Vitaliy_Khutoryanskiy
Processes which convert waste plastic into new items
separately for recycling. Plastic waste consists of various polymer types. Polyolefins make up nearly 50% of all plastic waste and more than 90% of waste is
Plastic_recycling
X-ray diffraction, and mass spectrometry are used to identify common functional groups. Polymer morphology is a microscale property that is largely dictated
Polymer_characterization
Polymer produced via a condensation reaction
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Condensation_polymer
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Living free-radical polymerization
Living_free-radical_polymerization
Chemical element with atomic number 22 (Ti)
titanium(III) chloride (TiCl3), which is used as a catalyst for production of polyolefins (see Ziegler–Natta catalyst) and a reducing agent in organic chemistry
Titanium
Substance composed of macromolecules with repeating structural units
a diameter in the range of 0.05 to 1 mm. The type and arrangement of (functional) residues of the repeat units effects or determines the crystallinity
Polymer
Type of hydrogel
from hydrophilic monomers by either chain or step growth, along with a functional crosslinker to promote network formation. A net-like structure along with
Self-healing_hydrogels
Applied protection for softer materials
with a combination of primer and clear coat. The primer is often made of polyolefin-resin, while the clear coat typically contains the additives siloxane
Anti-scratch_coating
Field of physics that studies polymers
Condensation polymerization Addition polymerization Classification Functional type Polyolefin Polyethylene Polypropylene Polyisobutylene Polyurethane Polyester
Polymer_physics
Stabilizer added to polymeric materials
stabilize thermal degradation. Even though HALS are extremely effective in polyolefins, polyethylene and polyurethane, they are ineffective in polyvinyl chloride
Polymer_stabilizer
branching that occurs during polymerisation can be influenced by the functionality of the monomers that are used. For example, in a free radical polymerisation
Polymer_architecture
Polymer derived from more than one species of monomer
and branching pattern. IR spectroscopy is primarily used to identify functional groups attached to a copolymer, but it can also provide information about
Copolymer
Highly viscous liquid exhibiting a kind of semi-solid behavior
approximately the density of water. Polyionic polymers are polymers with an ionic functional group. The ionic charges prevent the formation of tightly coiled polymer
Gel
Polymerization mechanism
The type of polymerization of a given monomer usually depends on the functional groups present, and sometimes also on whether the monomer is linear or
Chain-growth_polymerization
Cleavage of C=C, C≡C, or N=N bonds with ozone
considerations. Ozonolysis has been used to characterize the structure of some polyolefins. Early experiments showed that the repeat unit in natural rubber was
Ozonolysis
Scientist
Crain. Retrieved 27 August 2022. Baldwin, F. P.; Strate, G. V. (1972). "Polyolefin elastomers based on ethylene and propylene". Rubber Chemistry and Technology
Francis_P._Baldwin
Dutch physical chemist
polymerization catalysis, using that polymerization and crystallization of polyolefins on flat model catalysts serves as an effective method for investigating
J.W._Niemantsverdriet
mechanics — Product grade F [Withdrawn without replacement] ISO 4167:2012 Polyolefin agricultural twines ISO 4168:2002 Timekeeping instruments — Conditions
List of ISO standards 3000–4999
List_of_ISO_standards_3000–4999
Standards produced by BSI Group
Responsible Innovation – Guide PAS 9017: Plastics – Biodegradation of polyolefins in an open-air terrestrial environment – Specification PAS 1881: Assuring
British_Standards
Coating used to protect steel from corrosion
225 to 245 °C (437 to 473 °F). When used as a primer in a multi-layer polyolefin system, application temperature may be dropped based on FBE manufacturer's
Fusion_bonded_epoxy_coating
Motor vehicle
galvanized steel front fenders, hood, roof and door panels and thermoplastic polyolefin (TPO) bumper covers. The North American Regal weighs about 13 lb (6 kg)
Buick_Regal
Recycling of bottles made of polyethylene terephthalate
include oil, vinegar, milk, and shampoo. These bottles are closed with polyolefin screw closure with antitamper ring, and have a label which may be printed
PET_bottle_recycling
of equipment IEC 60708 Low-frequency cables with polyolefin insulation and moisture barrier polyolefin sheath IEC 60709 Nuclear power plants – Instrumentation
List_of_IEC_standards
American chemist (born 1928)
Diels-Alder structural goal, which provides the carbon framework for the functionalized cyclopentane ring. Later Corey developed an asymmetric Diels-Alder reaction
Elias_James_Corey
Substance applied to prevent adhesion to a surface
the moulded surface. Slip Additives are similarly used to prevent thin polyolefin films from adhering to metal surfaces (or each other) during processing
Release_agent
American chemist, material scientist, and academic
National University of Singapore, joining the faculty of the Institute for Functional Intelligent Materials initiated by Professor Konstantin Novoselov. In
Guillermo_Bazan
Class of organic compounds
creams. In addition, lactylates are bio-friendly additives for use in polyolefins, flame retardants, pigments, and PVC. Lactylates were developed in the
Lactylate
Hydrocarbon compound containing one or more C=C bonds
polyethylene and polypropylene. Polymers from alkene are usually referred to as polyolefins although they contain no olefins. Polymerization can proceed via diverse
Alkene
Chemical reaction that produces polymers
addition−fragmentation chain transfer was used to help synthesize end-functionalized polymers. Scientists began to realize the potential of RAFT in controlled
Reversible addition−fragmentation chain-transfer polymerization
Reversible_addition−fragmentation_chain-transfer_polymerization
Polycyclic organic compound having sterane as a core structure
Johnston JN (December 2005). "A case study in biomimetic total synthesis: polyolefin carbocyclizations to terpenes and steroids". Chemical Reviews. 105 (12):
Steroid
Polymerization process involving free radicals as repeating units
in Figure 23 illustrates the SFRP process. Because the chain end is functionalized with the TEMPO molecule (Figure 24), premature termination by coupling
Radical_polymerization
Type of chain polymerization
variety of monomers it can be carried out in the presence of certain functional groups the technique is rather simple and easy to control the reaction
Reversible-deactivation radical polymerization
Reversible-deactivation_radical_polymerization
Reaction in polymer chemistry
Nasir M. (June 2015). "Synthesis and application of polyethylene-based functionalized hyperbranched polymers". Progress in Polymer Science. 45: 23–43. doi:10
Chain_walking
Jamaican academic and university administrator
scientist at BASF. She was hired as a global technology analyst within the polyolefin catalysts market sector, and later became a chemical procurement manager
Tashni-Ann_Dubroy
Method of radical polymerization
bound to a secondary amine by an N-O single bond. The utility of this functional group is that under certain conditions, homolysis of the C-O bond can
Nitroxide-mediated radical polymerization
Nitroxide-mediated_radical_polymerization
Disposable undergarments designed for managing Nocturnal Enuresis
accidents. In 2021, inserts for girls were introduced with similar functionality. They fit inside a standard girls' underwear brief. As of 2025, the
Goodnites
Technology that converts waste plastic into carbon materials
hydrothermal synthesis for carbon nanotubes and hydrogen production from polyolefin plastics". Chemosphere. 297 134148. Bibcode:2022Chmsp.29734148V. doi:10
Plastic_carbonization
Textiles for medical and healthcare use
is preferred for stent implants due to its non-stick properties, while polyolefin is used for mesh implants. Vectran, a manufactured fiber from liquid-crystal
Medical_textiles
Thin, film-like structure separating two fluids, acting as a selective barrier
Handbook. Lancaster, PA.: echonomic Publishing Co., Inc. Membranes on Polyolefins Plants Vent Recovery, Improvement Economics Program. Intratec. 2012.
Membrane
Comprehensive list of compounds structurally related to fentanyl
"Paper Spray Mass Spectrometry Utilized with a Synthetic Microporous Polyolefin Silica Matrix Substrate in the Rapid Detection and Identification of More
List_of_fentanyl_analogues
American scientist
Brigitte Kay & Crowther, David George, "Durable Adhesive-based Ink-Printed Polyolefin Nonwovens", issued Dec. 9, 1997, assigned to Kimberly-Clark US patent
Richard_Yeo_(scientist)
Insulation material
panels using a binder (mostly synthetic such as polyester, polyurethane or polyolefin). The binder material can be new or recycled. Examples include cork, cotton
Building_insulation_material
Chemical process in which olefins are degraded with ethylene
{red}{\ce {CH2}}}+{\ce {MeO2C(CH2)7CH=}}{\color {red}{\ce {CH2}}}} Mixed polyolefins can be recycled via high selectivity isomerizing ethenolysation using
Ethenolysis
Material to reduce heat transfer in structures
commonly cellular materials are glass and foamed plastic like polystyrene, polyolefin, and polyurethane. Radiant barriers work in conjunction with an air space
Building_insulation
Award by the American Chemical Society, Rubber Division
University professor noted for contributions to understanding elastomeric polyolefins and rubber toughening of brittle polymers, and for founding the university's
Charles_Goodyear_Medal
Polymer showing drastic changes in physical properties with temperature
molecular origin of miscibility gaps. Thermoresponsive polymers can be functionalized with moieties that bind to specific biomolecules. The polymer-biomolecule
Temperature-responsive polymer
Temperature-responsive_polymer
Relative conformational uniformity of repeating units in a macromolecule
PMID 37775528. Coates, Geoffrey W. (2000-04-01). "Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts". Chemical Reviews.
Tacticity
Honorary award for scientists
synthesis of novel polymers, including chiral cyclopolymers and stereoblock polyolefins. The development of catalysts which change their structure as they work
Alan_T._Waterman_Award
unsuitable for drinking. linear low-density polyethylene - a member of the polyolefin family of plastics. It is a strong and flexible plastic and usually used
Glossary of environmental science
Glossary_of_environmental_science
Chain-growth polymerization without the ability to terminate
pp. 1022–1023. Coates, Geoffrey W. (April 2000). "Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts". Chemical Reviews.
Living_polymerization
FUNCTIONALIZED POLYOLEFINS
FUNCTIONALIZED POLYOLEFINS
FUNCTIONALIZED POLYOLEFINS
FUNCTIONALIZED POLYOLEFINS
Boy/Male
Hindu, Indian, Marathi, Sanskrit, Tamil
Divine Love; Supreme Love
Male
French
French form of Latin Desiderius, DIDIER means "longing."Â
Girl/Female
Muslim
Beautiful
Boy/Male
Hindu
Beautiful morning, The name of a star
Boy/Male
Muslim
Friend of Allah
Male
Dutch
, resolute helmet.
Girl/Female
Hindu, Indian, Tamil
Intelligent
Surname or Lastname
English
English : topographic name for someone who lived near a ford, Middle English, Old English ford, or a habitational name from one of the many places named with this word, such as Ford in Northumberland, Shropshire, and West Sussex, or Forde in Dorset.Irish : Anglicized form (quasi-translation) of various Gaelic names, for example Mac Giolla na Naomh ‘son of Gilla na Naomh’ (a personal name meaning ‘servant of the saints’), Mac Conshámha ‘son of Conshnámha’ (a personal name composed of the elements con ‘dog’ + snámh ‘to swim’), in all of which the final syllable was wrongly thought to be áth ‘ford’, and Ó Fuar(th)áin (see Foran).Jewish : Americanized form of one or more like-sounding Jewish surnames.Translation of German Fürth (see Furth).
Boy/Male
Hindu, Indian, Sanskrit
Always First
Boy/Male
Arabic, Bengali, Gujarati, Hindu, Indian, Kannada, Malayalam, Marathi, Muslim, Telugu
Moist; Hydrous; Clean Mind
FUNCTIONALIZED POLYOLEFINS
FUNCTIONALIZED POLYOLEFINS
FUNCTIONALIZED POLYOLEFINS
FUNCTIONALIZED POLYOLEFINS
FUNCTIONALIZED POLYOLEFINS
v. t.
To assign to some function or office.